Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (6): 1529-1539.DOI: 10.6023/cjoc201912029 Previous Articles     Next Articles

无过渡金属参与的炔烃环化反应研究进展

张磊a, 袁斯甜b, 王鹏c, 刘晋彪d   

  1. a 中南大学冶金与环境学院 长沙 410083;
    b 南昌海关技术中心 南昌 330002;
    c 嘉兴学院生物与化学工程学院 浙江嘉兴 314001;
    d 江西理工大学冶金与化学工程学院 江西赣州 341000
  • 收稿日期:2019-12-21 修回日期:2020-01-24 出版日期:2020-06-25 发布日期:2020-03-04
  • 通讯作者: 王鹏, 刘晋彪 E-mail:liujinbiao@jxust.edu.cn;815207636@qq.com
  • 基金资助:
    国家自然科学基金(Nos.21762018,21961014)、湖南省研究生创新(No.CX20190060)、中南大学中央高校基础研究基金及江西理工大学大学生创新创业训练计划(No.201910407015)资助项目.

Recent Advances in Cyclization Reaction of Alkynes under Transition Metal-Free Conditions

Zhang Leia, Yuan Sitianb, Wang Pengc, Liu Jinbiaod   

  1. a School of Metallurgy and Environment, Central South University, Changsha 410083;
    b Technology Center of Nanchang Customs, Nanchang 330002;
    c College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001;
    d School of Metallurgical and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000
  • Received:2019-12-21 Revised:2020-01-24 Online:2020-06-25 Published:2020-03-04
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Nos. 21762018, 21961014), the Hunan Provincial Innovation Foundation for Postgraduate (No. CX20190060), the Fundamental Research Funds for the Central Universities of Central South University, and the Innovation and Entrepreneurship Training Program of Jiangxi University of Science and Technology (No. 201910407015).

Remarkable achievements have been made in the construction of carbocyclic (heterocyclic) compounds through cyclization reaction of alkynes. It is vitally important to achieve the high selectivity of cyclization reactions, and neighboring group-participated selective cyclization reaction of alkynes is widely considered as an effective strategy. In this review, the recent advances in neighboring group-participated cyclization reaction of alkynes under transition metal-free conditions are summarized.

Key words: alkynes, neighboring group, transition metal-free, cyclization reaction