Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (5): 1751-1760.DOI: 10.6023/cjoc202212022 Previous Articles     Next Articles

Special Issue: 有机硼化学专辑



李思达a,c, 舒兴中b,*(), 吴立朋a,*()   

  1. a 中国科学院兰州化学物理研究所 羰基合成与选择氧化国家重点实验室 兰州 73000
    b 兰州大学化学化工学院 功能有机分子化学国家重点实验室 兰州 73000
    c 中国科学院大学 北京 100049
  • 收稿日期:2022-12-16 修回日期:2023-01-09 发布日期:2023-01-18
  • 通讯作者: 舒兴中, 吴立朋
  • 基金资助:
    国家自然科学基金(22271295); 中国科学院兰州化学物理研究所青年科技工作者协同创新联盟合作基金(HZJJ21-01)

Zirconium and Titanium Mediated Hydroboration of Alkenes and Alkynes

Sida Lia,c, Xing-Zhong Shub(), Lipeng Wua()   

  1. a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000
    b State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000
    c University of Chinese Academy of Sciences, Beijing 100049
  • Received:2022-12-16 Revised:2023-01-09 Published:2023-01-18
  • Contact: Xing-Zhong Shu, Lipeng Wu
  • Supported by:
    National Natural Science Foundation of China(22271295); Cooperation Foundation of Lanzhou Institute of Chemical Physics for Young Scholars(HZJJ21-01)

The transition metal-catalyzed hydroboration of alkenes and alkynes is one of the most efficient way for the production of boronate esters. This type of reaction is 100% atom economic, the starting material is readily available, and the products are diverse. It is noticed that most of the known catalytic systems are based on late-transition-metals such as Rh, Ir, Pd, Pt, Co, Fe and Cu. The use of early-transition-metals of zirconium and titanium, on the other hand, is very scarce. In this short review, the development of application in zirconium and titanium mediated hydroboration of alkene and alkyne is summarized, and the research trends of this area are also discussed.

Key words: zirconium, titanium, alkenes, alkynes, hydroboration