Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (8): 2338-2352.DOI: 10.6023/cjoc202002010 Previous Articles     Next Articles

N-磺酰-1,2,3-三唑的合成方法及其在有机合成中的应用研究进展

张文生a, 许文静b, 张斐c, 马春玉a, 马科友a, 李焱b   

  1. a 济源职业技术学院冶金化工系 河南济源 459000;
    b 焦作师范高等专科学校 合成技术研究所 河南焦作 454100;
    c 焦作职业技术学校 河南焦作 454100
  • 收稿日期:2020-02-10 修回日期:2020-04-16 出版日期:2020-08-25 发布日期:2020-05-11
  • 通讯作者: 张文生 E-mail:tongjizws@163.com
  • 基金资助:
    河南省教育厅自然科学重点研究计划(No.20B150014)和济源职业技术学院2020年重点科研课题(No.JZXY-2020-58)资助项目.

Progress in Synthesis of N-Sulfonyl-1,2,3-triazole and Its Application in Organic Synthesis

Zhang Wenshenga, Xu Wenjingb, Zhang Feic, Ma Chunyua, Ma Keyoua, Li Yanb   

  1. a Department of Metallurgy and Chemical Engineering, Jiyuan Vocational and Technical College, Jiyuan, Henan 459000;
    b Institute of Synthetic Technology, Jiaozuo Teachers College, Jiaozuo, Henan 454100;
    c Jiaozuo Vocational and Technological School, Jiaozuo, Henan 454100
  • Received:2020-02-10 Revised:2020-04-16 Online:2020-08-25 Published:2020-05-11
  • Supported by:
    Project supported by the Key Natural Science Research Program of Henan Education Department (No. 20B150014) and the Key Scientific Research Projects of Jiyuan Vocational and Technical College (No. JZXY-2020-58).

N-Sulfonyl-1,2,3-triazole, an important class of five-membered nitrogen-containing organic compounds, has been found processing widespread application in the synthesis of various nitrogen-containing organic compounds, especially heterocyclic or amino-substituted aromatic rings. The synthetic methods of N-sulfonyl-1,2,3-triazole are introduced. Besides, the progress on constructions of various organic compounds via ring-opening reaction of N-sulfonyl-1,2,3-triazoles as precursor of α-diazoimine and Rh-carbene imine intermediates in the past two years is reviewed.

Key words: N-sulfonyl-1,2,3-triazole, α-diazoimine, Rh-carbene imine