Recent Advances in Trifluoromethoxylation Reactions

doi:10.6023/cjoc202003048

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (7): 1805-1813.DOI: 10.6023/cjoc202003048 Previous Articles Next Articles

ACCOUNTS

三氟甲氧基化反应研究进展

王丰, 汤平平

南开大学化学学院元素有机化学国家重点实验室天津 300071

收稿日期:2020-03-20 修回日期:2020-04-24 发布日期:2020-04-30
通讯作者: 汤平平 E-mail:ptang@nankai.edu.cn
基金资助:
国家重点研发计划（No.2016YFA0602900）、国家自然科学基金（Nos.21672110，21925105）及天津市自然科学基金（No.18JCJQJC47000）资助项目.

Recent Advances in Trifluoromethoxylation Reactions

Wang Feng, Tang Pingping

State Key Laboratory of Elemento-organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071

Received:2020-03-20 Revised:2020-04-24 Published:2020-04-30
Supported by:
Project supported by the National Key Research and Development Program of China (No. 2016YFA0602900), the National Natural Science Foundation of China (Nos. 21672110, 21925105) and the Natural Science Foundation of Tianjin City (No. 18JCJQJC47000).

In recent years, the field of organic fluorine chemistry has developed rapidly. Fluorination and fluorine-containing functionalization reactions have attracted extensive attention of organic chemists due to their special physical and chemical properties. The introduction of fluorine-containing group into drug molecules can improve the biological activity of drug molecules. Trifluoromethoxy group has strong electron absorption and high lipophilicity, compounds containing trifluoromethoxy play an important role in the fields of medicine, pesticides and materials. In recent years, some innovative strategies have been used to synthesize compounds containing trifluoromethoxy group. This account mainly focuses on the research of trifluoromethoxy reaction in our group, and some challenges faced by trifluoromethoxy reaction.

Key words: trifluoromethoxylation, trifluoromethyl aryl sulfonate (TFMS), (E)-O-trifluoromethyl-benzaldoximes (TFBO)

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Wang Feng, Tang Pingping. Recent Advances in Trifluoromethoxylation Reactions[J]. Chinese Journal of Organic Chemistry, 2020, 40(7): 1805-1813.

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三氟甲氧基化反应研究进展

Recent Advances in Trifluoromethoxylation Reactions

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