Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (1): 126-143.DOI: 10.6023/cjoc202006021 Previous Articles     Next Articles



仝明慧a, 张欣宇a, 王也铭b,*(), 王自坤a,*()   

  1. a 东北师范大学化学学院 长春 130024
    b 吉林工程技术师范学院 化学与工业生物工程交叉学科研究院 长春 130052
  • 收稿日期:2020-06-12 修回日期:2020-07-15 发布日期:2020-08-19
  • 通讯作者: 王也铭, 王自坤
  • 作者简介:
    * Corresponding authors. E-mail: ;
  • 基金资助:
    吉林省科技厅基金基金(20190103128JH); 中央高校基本科研业务费专项资金(2412019FZ006)

Advances in Reactions of Iodonium Ylides

Minghui Tonga, Xinyu Zhanga, Yeming Wangb,*(), Zikun Wanga,*()   

  1. a Faculty of Chemistry, Northeast Normal University, Changchun 130024
    b Institute of Chemical and Industrial Bioengineering, Jilin Engineering Normal University, Changchun 130052
  • Received:2020-06-12 Revised:2020-07-15 Published:2020-08-19
  • Contact: Yeming Wang, Zikun Wang
  • Supported by:
    the Department of Science and Technology of Jilin Province(20190103128JH); the Fundamental Research Funds for the Central Universities(2412019FZ006)

Since the first reaction involved ylides was reported, they have been an important research direction of organic chemistry. Among them, iodonium ylides attracted considerable attentions in organic synthesis due to their unique reactivities as both iodine source and ylides. The preparation methods and structural properties of iodonium ylides are generally elaborated. Then, the reactivities of iodonium ylides are reviewed in detal, including the application of iodonium ylides as a carbene precursor in insertion reactions, cyclopropane reactions, and their development research in cycloaddition reactions, rearrangement reactions and halogenation reaction.

Key words: iodonium ylide, insertion reaction, cycloaddition reaction, rearrangement reaction, trifluoromethylthiolation