Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (4): 1639-1645.DOI: 10.6023/cjoc202008032 Previous Articles     Next Articles



黄杰军a,c, 钱蓉蓉b, 王爽a, 曹洪恩a,*()   

  1. a 扬州大学园艺与植物保护学院 江苏扬州 225009
    b 江苏旅游职业学院 江苏扬州 225127
    c 江苏扬农化工集团有限公司 江苏扬州 225009
  • 收稿日期:2020-08-18 修回日期:2020-09-26 发布日期:2020-12-19
  • 通讯作者: 曹洪恩
  • 基金资助:
    国家重点研发计划(2018YFD0200100); 江苏省高校优势学科建设工程资助项目

Polyselenide-Catalyzed Cyclohexene Oxidation to Produce 1,2-Cyclohexanediol

Jiejun Huanga,c, Rongrong Qianb, Shuang Wanga, Hong'en Caoa,*()   

  1. a School of Horticulture and Plant Protection, Yangzhou University, Yangzhou, Jiangsu 225009
    b Jiangsu College of Tourism, Yangzhou, Jiangsu 225127
    c Jiangsu Yangnong Chemical Group Co. Ltd, Yangzhou, Jiangsu 225009
  • Received:2020-08-18 Revised:2020-09-26 Published:2020-12-19
  • Contact: Hong'en Cao
  • About author:
    * Corresponding author. E-mail:
  • Supported by:
    National Key Research and Development Program of China(2018YFD0200100); Priority Academic Program Development of Jiangsu Higher Education Institutions

A new method for one-step synthesis of polyselenide was developed. The material was found to be an efficient and recyclable catalyst for the dihydroxylation of cyclohexene to produce 1,2-cyclohexanediol, which was an important inter- mediate for the synthesis of many fine chemicals. Interestingly, the unique structure of the catalyst at molecular level resulted in a novel free-radical reaction methanism allowing the utilization of O2 as the supplementary oxidant, which was quite different from most of the reported organoselenium-catalyzed reactions.

Key words: selenium, polyselenide, cyclohexene, 1,2-cyclohexanediol, green oxidation