Access to Cyclohexane-1,2-diol through the Diphenyldiselenide Catalyzed Oxidation of Cyclohexene by Hydrogen Peroxide

doi:10.6023/cjoc2012012049

Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (05): 1096-1099.DOI: 10.6023/cjoc2012012049 Previous Articles Next Articles

Notes

二苯基二硒醚催化双氧水氧化环己烯合成1,2-环己二醇

俞磊^a,b,c, 王俊^b, 陈天^b, 丁克鸿^c, 潘毅^a

a 南京大学化学化工学院南京 210093;
b 扬州大学化学化工学院扬州 225002;
c 江苏扬农化工集团有限公司扬州 225009

收稿日期:2012-12-30 修回日期:2013-01-16 发布日期:2013-01-25
通讯作者: 俞磊,yulei@yzu.edu.cn E-mail:yulei@yzu.edu.cn
基金资助:
国家自然科学基金(No. 21202141)、江苏省高校优势学科项目、江苏省环境材料与工程重点实验室开放基金(Nos. K11024, K090030)资助项目.

Access to Cyclohexane-1,2-diol through the Diphenyldiselenide Catalyzed Oxidation of Cyclohexene by Hydrogen Peroxide

Yu Lei^a,b,c, Wang Jun^b, Chen Tian^b, Ding Kehong^c, Pan Yi^a

a School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093;
b School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002;
c Jiangsu Yangnong Chemical Engineering Co. Ltd., Yangzhou 225009

Received:2012-12-30 Revised:2013-01-16 Published:2013-01-25
Supported by:
Project supported by the National Natural Science Fundation of China (No. 21202141), the Priority Academic Program Development of Jiangsu Higher Education Institutions, the Opening Foundation of the Key Laboratory of Environmental Materials and Engineering of Jiangsu Province (Nos. K11024, K090030).

The diphenyldiselenide catalyzed oxidation of cyclohexene by hydrogen peroxide led to cyclohexane-1,2-diol with high conversion and selectivity. Compared with traditional metal catalyst, selenium catalysts are cheaper and less harmful to environment. This synthetic method is also clean and highly atom-economic. Therefore, this reaction is highly applicable.

Key words: selenium, catalysis, green chemistry, cyclohexane-1,2-diol, oxidation

Cite this article

Yu Lei, Wang Jun, Chen Tian, Ding Kehong, Pan Yi. Access to Cyclohexane-1,2-diol through the Diphenyldiselenide Catalyzed Oxidation of Cyclohexene by Hydrogen Peroxide[J]. Chin. J. Org. Chem., 2013, 33(05): 1096-1099.

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二苯基二硒醚催化双氧水氧化环己烯合成1,2-环己二醇

Access to Cyclohexane-1,2-diol through the Diphenyldiselenide Catalyzed Oxidation of Cyclohexene by Hydrogen Peroxide

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