Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (12): 4773-4779.DOI: 10.6023/cjoc202109037 Previous Articles     Next Articles

ARTICLES

对甲苯硫酚/三环己基膦介导的硝基芳烃的光化学还原反应

鲍兆伟, 吕洁, 金智超*()   

  1. 贵州大学绿色农药与农业生物工程国家重点实验室培育基地教育部绿色农药与农业生物工程重点实验室 贵阳 550025
  • 收稿日期:2021-09-24 修回日期:2021-10-26 发布日期:2021-11-03
  • 通讯作者: 金智超
  • 基金资助:
    国家自然科学基金(21801051); 国家自然科学基金(21961006); 国家自然科学基金(32172459); 贵州省科技技术基金(黔科合基础-ZK[2021]重点033)

Photochemical Reduction of Nitroaromatics Mediated by p-Toluenethiol/PCy3

Zhaowei Bao, Jie Lü, Zhichao Jin()   

  1. State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering, Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University, Guiyang 550025
  • Received:2021-09-24 Revised:2021-10-26 Published:2021-11-03
  • Contact: Zhichao Jin
  • Supported by:
    National Natural Science Foundation of China(21801051); National Natural Science Foundation of China(21961006); National Natural Science Foundation of China(32172459); Science and Technology Department of Guizhou Province(黔科合基础-ZK[2021]重点033)

A new photochemical reduction of nitroaromatics mediated by p-toluenethiol and PCy3 under solvent-free, metal-free, and mild conditions is reported for the first time. This reaction has shown good generalities, and amine derivatives with different substituents and substitution patterns can be obtained in good yields. Therefore, this reduction method represents a potentially valuable new strategy for the efficient synthesis of amine compounds.

Key words: nitroaromatics, reduction, photochemistry, aromatic amines