Chin. J. Org. Chem. ›› 1987, Vol. 7 ›› Issue (5): 376-377. Previous Articles     Next Articles

Ph3P/Mo[VI]体系对亚砜类的脱氧反应

陆熙炎;陶晓春   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1987-10-25

Mo(VI)-PPh3 catalyzed deoxygenation of sulfoxides

LU XIYAN;TAO XIAOCHUN   

  • Published:1987-10-25

Refluxing R2SO (R = Me, Ph, PhCH2, n-octyl, etc.) with MoO2(SCNEt2)2 and PPh3 in benzene gave 63-97% sulfides R2S.

Key words: SULFOXIDE, BINARY SYSTEM, MOLYBDENUM COMPLEX, TRIPHENYLPHOSPHINE, DEOXIDIZATION, NITROGENASE

CLC Number: