Palladium-Catalyzed Synthesis of 2-Hydroxyphenyl Vinylferrocene

doi:10.6023/cjoc201407003

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (1): 228-231.DOI: 10.6023/cjoc201407003 Previous Articles Next Articles

Notes

钯催化2-羟基苯基二茂铁乙烯的合成

刘世娟, 马文兵, 郑志花, 马忠平, 曹端林

中北大学化工与环境学院太原 030051

收稿日期:2014-07-02 修回日期:2014-09-03 发布日期:2014-09-18
通讯作者: 马文兵, 曹端林 E-mail:mawenbing@nuc.edu.cn;cdl@nuc.edu.cn

Palladium-Catalyzed Synthesis of 2-Hydroxyphenyl Vinylferrocene

Liu Shijuan, Ma Wenbing, Zheng Zhihua, Ma Zhongping, Cao Duanlin

School of Chemical and Environmental Engineering, North University of China, Taiyuan 030051

Received:2014-07-02 Revised:2014-09-03 Published:2014-09-18

1. Palladium-Catalyzed Synthesis of 2-Hydroxyphenyl Vinylferrocene.PDF(1625KB)

Abstract

A Pd-catalyzed method was developed for Heck-type cross-coupling reaction of a wide range of o-iodo(bromo)- phenols with vinylferrocene. The influences of different palladium catalyst, bases, solvents and other conditions were investigated. In the presence of PdCl₂(dppf), Cs₂CO₃ and CH₃CN, the cross-coupling products can be obtained in moderate to good yields. This catalyst system exhibits good activity in the synthesis of o-hydroxyphenyl vinylferrocene compounds.

Key words: Heck-type cross-coupling reaction, vinylferrocene, o-iodo(bromo)phenols, palladium-catalyzed

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Liu Shijuan, Ma Wenbing, Zheng Zhihua, Ma Zhongping, Cao Duanlin. Palladium-Catalyzed Synthesis of 2-Hydroxyphenyl Vinylferrocene[J]. Chin. J. Org. Chem., 2015, 35(1): 228-231.

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钯催化2-羟基苯基二茂铁乙烯的合成

Palladium-Catalyzed Synthesis of 2-Hydroxyphenyl Vinylferrocene

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