Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (11): 2095-2098.DOI: 10.6023/cjoc201206020 Previous Articles     Next Articles



晏利琴, 张平, 冯寅寅, 商永嘉   

  1. 安徽师范大学化学与材料科学学院 芜湖 241000
  • 收稿日期:2012-06-19 修回日期:2012-07-20 发布日期:2012-07-29
  • 通讯作者: 商永嘉
  • 基金资助:

    国家自然科学基金(No. 21172001)资助项目.

Study on the Dehydrate Amination of Alcohols in Water Using Sulfonic Calix[6]resorcinarene

Yan Liqin, Zhang Ping, Feng Yinyin, Shang Yongjia   

  1. College of Chemistry and Materials Science, Anhui Normal University, Wuhu 230061
  • Received:2012-06-19 Revised:2012-07-20 Published:2012-07-29
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21172001).

The dehydrate amination of alcohols was investigated in water using sulfonic calix[6]resorcinarene and acid. A series of aminations were synthesized in high yields. The structures were characterized by 1H NMR and 13C NMR speetra. Water-soluble sulfonic calix[6]resorcinarene could be reused times and without a loss of catalytic efficiency.

Key words: sulfonic calix[6]resorcinarene, host-guest systems, green-chemistry, phase-transfer catalysts, aminations