Oxidative Cross Coupling of sp3-C—H Bonds Catalyzed by Bu4NAuCl4 with H2O2 as Oxidant

doi:10.6023/cjoc201210029

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (11): 2090-2094.DOI: 10.6023/cjoc201210029 Previous Articles Next Articles

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Bu₄NAuCl₄催化的H₂O₂氧化的sp³-C—H键与sp³-C—H键的交叉偶联反应

张艳^a,b, 朱成建^b

a 江南大学医药学院无锡 214122;
b 南京大学化学化工学院南京 210093

收稿日期:2012-10-17 修回日期:2012-10-29 发布日期:2012-10-31
通讯作者: 张艳 E-mail:zhangyanchem@163.com
基金资助:
国家自然科学基金(No. 21074054)和2012江苏省大学生创新训练资助项目.

Oxidative Cross Coupling of sp³-C—H Bonds Catalyzed by Bu₄NAuCl₄ with H₂O₂ as Oxidant

Zhang Yan^a,b, Zhu Chengjian^b

a School of Medicine and Pharmaceutics, Jiangnan University, Wuxi 214122;
b State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093

Received:2012-10-17 Revised:2012-10-29 Published:2012-10-31
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21074054) and the Innovation Experiment Program for University Students of Jiangsu Province.

Activation of two sp³-C—H bonds and oxidative alkylation of sp³-C—H bond adjacent to a nitrogen atom of tertiary amine were catalyzed by Bu₄NAuCl₄ with H₂O₂ as oxidant under mild reaction conditions. The safe, convenient, and environmentally benign process, as well as the broad substrate scope, low catalyst loading, high selectivity, short reaction time, and good yields make the protocol very practical.

Key words: sp³-C—H activation, cross-dehydrogenative coupling, oxidative alkylation, gold catalyst

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Zhang Yan, Zhu Chengjian. Oxidative Cross Coupling of sp³-C—H Bonds Catalyzed by Bu₄NAuCl₄ with H₂O₂ as Oxidant[J]. Chin. J. Org. Chem., 2012, 32(11): 2090-2094.

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Bu₄NAuCl₄催化的H₂O₂氧化的sp³-C—H键与sp³-C—H键的交叉偶联反应

Oxidative Cross Coupling of sp³-C—H Bonds Catalyzed by Bu₄NAuCl₄ with H₂O₂ as Oxidant

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Bu4NAuCl4催化的H2O2氧化的sp3-C—H键与sp3-C—H键的交叉偶联反应