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化学学报
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化学学报 ›› 1956, Vol. 22 ›› Issue (4): 299-304. 上一篇    下一篇

论文

天目山藜蘆中的植物鹼

朱任宏, 王友海   

  1. 中国科学院药物研究所 上海
  • 投稿日期:1956-05-04 发布日期:2013-06-04

THE ALKALOIDS OF CHINESE DRUG, LI-LU, VERATRUM SPP.

CHU JEN-HUNG, WANG YU-HAI   

  1. Institute of Materia Medica, Academia Sinica, Shanghai
  • Received:1956-05-04 Published:2013-06-04

PDF

651

被引次数

10

從天目山藜廬中分得两种新植物鹼,暂命名为天目藜廬鹼甲和天目藜廬鹼乙.前者实验式为C27H43ON,熔點172—174°,[a]D16=-99.3°,已製成其结晶的盐酸盐等.後者的实验式为C34H51O8N,熔點231°,[a]D13=+24°,亦已製成其结晶的盐酸盐等.当天目藜廬鹼乙水解後,可得其结晶的胺鹼的盐酸盐,熔點192°.另從上海购买的藜廬中,分得一金黄色针状色素,实验式为C10H8O3,熔點172°,已製成其结晶的乙酸酯和溴化物.

Two new crystalline alkaloids were isolated from the Chinex drug, Li-lu, Veratrum spp., collected from Mount Tien-Mu, Chekiang Province.They are provisionally named tienmulil mine and tienmulilminine respectivel.The formula for the former is C27H43ON, m.p.172°-174°, and [α]16D=-99.3°(in CH3OH, 6.44%).