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化学学报
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化学学报 ›› 1957, Vol. 23 ›› Issue (5): 351-360. 上一篇    下一篇

论文

一些二氢萘的衍生物及其结构

蔣錫夔   

  1. 中国科学院化学研究所
  • 投稿日期:1957-03-25 发布日期:2013-06-03

SOME DERIVATIVES OF DIHYDRONAPHTHALENE AND THE PROOF OF THEIR STRUCTURES

STANLEY HSI-KWEI JIANG   

  1. Institute of Chemistry, Academia Sinica, Peking
  • Received:1957-03-25 Published:2013-06-03

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本文报告一些二氢萘衍生物的合成,并根据它们的化学变化关系与光谱证明其结构。本文又报告一些双酯VI的热解反应,并且得到一些相当于单体Ⅱ的高分子化合物。

A number of the derivatives of dihydron aphthalono were prepared; their structures were established through chemical transformations (see flow sheet) and by their spectral data (fig.1, tables 1 and 2).The previous assignment of structure Ⅲ to their carbonation product by Walker and Scott[2] is shown to be incorrect Pyrolyses of the various diesters Ⅵ are reported.The polymor of benz-p-quinodimothane (Ⅱ) was obtainod in small amounts.