化学学报 ›› 1958, Vol. 24 ›› Issue (2): 123-125.    下一篇

论文

锑氧化物Ⅰ.——Harries的双焦没食子酚及其锑氧化物

袁开基   

  1. 上海第一医学院药学系有机化学教研组
  • 投稿日期:1957-04-04 发布日期:2013-06-03

ANTIMONYL COMPOUNDS Ⅰ. HARRIES’ DIPYROGALLOL AND ITS ANTIMONYL COMPOUND

YUAN KAI-CHI(KECHEE C. YUEN)   

  1. Department of Organic Chemistry, School of Pharmacy, the First Medical College of Shanghai
  • Received:1957-04-04 Published:2013-06-03

Harries的双焦没食子酚虽按结构可能按几种方式结合几个锑原子,但和三氯化锑或吐酒石都只能结合一个锑原子,产品都是1:1锑氧化物。此物能被3N盐酸脱锑,但能用2N盐酸重结晶。游离的Harries的双焦没食子酚有无水物及一水化物两种结晶。

Harries' dipyrogallol or 2,3,4,2',3',4'-hexahydroxydiphenyl,though a compound with the possibility of multiple antimonation on the odiphenol units,forms with either excess of antimony trichloride in saturated sodium chloride or excess of tartar emetic in aqueous solution,a sole 1:1 antimonyl compound.The antimonyl dipy rogallol is almost insoluble in N hydrochloric acid,but can be recrystallized with 2N hydrochloric acid,whereas in 3 N (or more concentrated) hydrochloric acid,it is completely hydrolyzed,regenerating quantitatively the original dipyrogallol.Harries' dipyrogallol has been found to crystallize in two forms:the needles (anhydrous),and the prisms (monohydrate).