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化学学报
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化学学报 ›› 1959, Vol. 25 ›› Issue (2): 81-84.    下一篇

论文

六氯锑酸钠的制备法

顾翼东1, 谢高阳1, 王秉新2   

  1. 1. 复旦大学化学系;
    2. 华东纺织工学院染化系
  • 投稿日期:1957-07-09 发布日期:2013-06-03

THE PREPARATION OF SODIUM HEXACHLOROANTIMONATE(Ⅴ)

KU YIT-TONE1, HSIEH KAO YANG1, WANG PING-SHING2   

  1. 1. Department of Chemistry, Fu-tan University, Shanghai;
    2. Department of Textile Finishing and Chemical Fibers. East China Textile Institute, Shanghai
  • Received:1957-07-09 Published:2013-06-03

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被引次数

2

六氯锑酸钠的制备条件颇严格, 须用三克分子五氯化锑, 加于含一克分子氯化钠的2N盐酸溶液中.盐酸的用量也须适当控制.其分子式是 NaSbCl6·5H2O.作微黄色针状晶体.性质与钾盐相类似, 只是溶解度较大, 晶体的保存亦较难.

Among the monovalent salt.e of hegachloroantimonic acid, lithium, potaesinm, rubidium, cesium and ammonium salts have been described in the literature tho preparation of the corresponding sodium salt has not yet been successful.It is now found that the sodium salt can likewise be prepared, but the conditions required are much more delicate.