化学学报 ›› 1959, Vol. 25 ›› Issue (4): 197-204. 上一篇    下一篇

论文

甲基氯硅烷的乙醇解速度

江英彦, 林一, 王葆仁   

  1. 中国科学院化学研究所
  • 投稿日期:1959-02-18 发布日期:2013-06-03

THE REACTION VELOCITY OF THE ETHANOLYSIS OF METHYLCHLOROSILANES

CHIANG YIN-YEN, LIN I, WANG PAO-JEN   

  1. Institute of Chemistry, Academia Sinica
  • Received:1959-02-18 Published:2013-06-03

(1)二甲基二氯硅烷和甲基三氯硅烷的部分醇解,产物的收率很高,达到97.7—98.9%。用分馏方法可以确定各步产物的成分,因此可以应用Fuoss方程式计算这两种氯硅烷逐步竞争醇解的反应速度常数比。

Polymethylsiloxanes constitute a class of organosilicon polymers of primary importance. They include linear oils and rubbors and the three dimensional resins. With the exception of the rubbers, the preparation of the oils and resins are done by hydrolyzing a mixture of methylchlorosilanes of different functionalities. By varying the proportion of the monomers, it is possible to obtain polymers of different molecular weights with different degreo of branching and cross-linking.