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化学学报
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化学学报 ›› 1961, Vol. 27 ›› Issue (2): 93-96.    下一篇

溶液中络合物的平衡理论

徐光宪   

  1. 北京大学
  • 投稿日期:1959-06-06 发布日期:2013-06-03

A THEORY OF EQUILIBRIA OF COMPLEXES IN SOLUTION

HSU KWANG-HSIEN   

  1. Peking University
  • Received:1959-06-06 Published:2013-06-03

PDF

675

被引次数

10

本文提出用类似Freundlich的吸附公式表达溶液中络合作用和配位体浓度之间的关系,同时反过来从分级平衡理论讨论Langmuir,Freundlich,BET等公式之间的联系.

A theoretical expression, similar to the Freundlich adsorption isotherm, has been proposed to express the change of half wave potentials, oxidation-reduction potentials, solubilities,etc., as a result of complex formation in solution.