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化学学报
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化学学报 ›› 1961, Vol. 27 ›› Issue (3): 185-189. 上一篇    下一篇

论文

1, 1’-二氰基联环己烷的反应

黄葆同   

  1. 中国科学院应用化学研究所
  • 投稿日期:1960-05-10 发布日期:2013-06-03

SOME REACTIONS OF 1, 1’-DICYANOBICYCLOHEXYL

HUANG PAO-TUNG   

  1. Institute of Applied Chemistry, Academia Sinica
  • Received:1960-05-10 Published:2013-06-03

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从1, 1'-二氰基联环己烷(Ⅲ)经水解初次得到相应的二羧酸(Ⅴ)及酸酐(Ⅵ), 由二元酸(Ⅴ)经氢化锂铝还原得二元醇(Ⅶ), 后者用硫酸脱水得螺烷(Ⅷ).

Hydrolysis of 1, 1'-dicyanobicyclohexyl(Ⅲ) afforded for the first time the correspondiun dicarbozylic acid(Ⅴ) and its and its dride(Ⅵ).Upon oe reduction of the dicarboxylic acid with lithium aluminum hydride, the dihydric alcohol(Ⅶ) was ohtained.The latter was dehydrated with sulphuric acid to give the spiro compound(Ⅷ).