化学学报 ›› 1964, Vol. 30 ›› Issue (5): 496-499. 上一篇    下一篇

研究简报

圓形紙层析法的研究 Ⅲ.氯、溴、碘和硫氰酸根的分离

毛志翔   

  1. 浙江医科大学
  • 投稿日期:1963-10-14 修回日期:1964-04-21 发布日期:2013-06-03

STUDIES ON CIRCULAR PAPER CHROMATOGRAPHY Ⅲ. THE SEPARATION OF CHLORIDE, BROMIDE, IODIDE, AND THIOCYANATE IONS

MAO CHIH-HSIANG   

  1. The Medical College of Chekiang
  • Received:1963-10-14 Revised:1964-04-21 Published:2013-06-03

关于氯、溴、碘和硫氰酸根离子的纸层析法,Lederer[1]和仲野[2]等曾有报告。本文采用后者的正丁醇—丙酮—氢氧化铵展开剂,着重研究氢氧化銨浓度改变时,对上述四离子圆形纸层析的影响,结果指出,如将其中氢氧化铵的浓度降低至仅l/10时,同样可以获得良好的分离。

The present paper deals with the separation of chloride, bromide, iodide, and thio-cyanate ions by the circular paper chromatographic method (Giri). Two series of eluents have been tested. One is the mixture of n-butanol, acetone, and ammonium hydroaide (3:13:4);the concentration of the latter can be 1.5, 3, 6, 9, 12 or 15 N. Good separation can be achieved with Hsin-Hua(新华)No.1 "Fast" filter paper and What-man No. 1 filter paper when the anions mentioned were chromatographed either singly or admixed. It has been found experimentally that the Rfc values of these anions were not greatly influenced by the basicity of the solvent as shown in Table 1 in the Chinese text. This solvent system is a modification of that used by Shoichi Nakano[2].