化学学报 ›› 1964, Vol. 30 ›› Issue (6): 584-586. 上一篇    下一篇

研究简报

甲酸-水体系的粘度

程镕时, 胡慧珍   

  1. 中国科学院应用化学研究所
  • 投稿日期:1964-01-02 发布日期:2013-06-03

THE VISCOSITY OF THE SYSTEM FORMIC ACID-WATER

CHENG YUNG-SHIH, HU HUI-TSENG   

  1. Institute of Applied Chemistry, Academia Sinica
  • Received:1964-01-02 Published:2013-06-03

甲酸-水二元混合液的粘度已有研究.最近Глаголева称粘度组成曲线在甲酸水的克分子比1:1和1:2处出现平台,认为是存在两种甲酸-水分子化合物.在早期工作中无此现象,因此作者重新测量甲酸-水体系在25°时的粘度.粘度测量使用Tsuda式水平粘度计.因为水平粘度计的驱动压力是外加恒压,粘度直接正比于外压与流过时间的乘积,不需要象用一般粘度计时另外测定液体密度再从比密粘度计算,从而消除密度测定所引起的误差.

The viscosities of the binary mixtures of formic acid-water were measured at 250 with horizontal viscometer under applied pressure.The viscosity increases continuously with increasing concentration of formic acid.The two platforms in the viscosity-composi- Lion curve at mole ratios 1:1 and 1:2 observed by Glagoleva have not been confirmed.For mixtures with formic acid concentration between 55 and 90%,the viscosity varies linearly with the weight fraction of formic acid and can be expressed as η25(cps)=0.633+1.007W.