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化学学报
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化学学报 ›› 1965, Vol. 31 ›› Issue (3): 236-245. 上一篇    下一篇

论文

不饱和碳氢化合物的水化反应——Ⅰ.三甲基乙烯在强酸溶液中的水化速度及反应机理

刘雲浦, 王正烈, 侯得顯   

  1. 天津大学化工系物理化学教研室
  • 投稿日期:1964-09-18 发布日期:2013-06-03

THE HYDRATION OF UNSATURATED HYDROCARBONS Ⅰ. THE HYDRATION RATE OF TRIMETHYLETHYLENE AND ITS REACTION MECHANISM IN AQUEOUS SOLUTIONS OF STRONG ACIDS

LIU YUN-PU, WANG CHENG-LIEH, HOU TEH-HSIEN   

  1. Department of Chemical Engineering, Tientsin University
  • Received:1964-09-18 Published:2013-06-03

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387

被引次数

1

本文对三甲基乙烯在25℃和不同浓度的盐酸(0.1-2.5M),高氯酸(0.1-2.5M),硫酸(0.25-2.5M)水溶液中,进行反应速度的测定。

The hydration rate of trimethylethylene is investigated in a wider range of hydrochloric (0.1-2.6 M),perchloric (0.1-2.5 M),and sulphuric (0.25-2.5 M) acid solutions.At constant acid strength,the rate is strictly of the first order with respect to the concentration of the olefin,while it increases rapidly with the increase of the acid concentration.