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化学学报
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化学学报 ›› 1978, Vol. 36 ›› Issue (2): 129-136. 上一篇    下一篇

论文

三尖杉属植物中生物碱的研究——Ⅱ.三尖杉(Cephalotaxus fortunei Hook.f.)中的四种微量生物碱的分离和鉴定及福建三尖杉碱的化学结构

马广恩1, 林隆泽1, 赵志远1, 范雪贞1,2   

  1. 1. 中国科学院上海药物研究所;
    2. 上海南昌制药厂
  • 投稿日期:1977-03-08 发布日期:2013-06-03

STUDIES ON ALKALOIDS OF CEPHALOTAXUS——Ⅱ.FOUR MINOR ALKALOIDS FROM CEPHALOTAXUS FORTUNEI HOOK.F.AND THE STRUCTURE OF CEPHALOFORTUNEINE

MA GUANG-EN1, LIN LUNG-TSE1, CHAO TSE-YUAN1, FAN HSUEH-CHEN1,2   

  1. 1. Shanghai Institute of Materia Medica, Academia Sinica;
    2. Shanghai Nanchang Pharmaceutical Works
  • Received:1977-03-08 Published:2013-06-03

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本文报导了三尖杉中分离得到的四种微量生物碱的理化性质.三尖杉碱-9(Ⅰ)、三尖杉碱-3(Ⅱ)分别鉴定为已知生物碱,11-羟基三尖杉碱和表-台湾三尖杉碱.三尖杉碱-15为一种新生物碱,命名为福建三尖杉碱(cephalofortuneine),经光谱分析(红外、紫外、核磁共振和质谱)推测其化学结构为Ⅳ.三尖杉碱-2的结构未定.

Four alkaloids isolated from egtraots of C.fortwraei Book.f.wer) described.Alkaloid CF-9(Ⅰ) and alkaloid CF-3 (Ⅱ) were identified as 11-hydrogycephalotagine and Phelline alkaloid-7 or epiwilsonine respectively.The alkaloid CF-15 is a new alkaloid of Homoerythrina type and named cephalofortuneine.Its strnoture is deduced from its UV, IR, NMR and MS spectra to be IV.The structuxe of alkaloid CF-2 is still under investigation.