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化学学报
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化学学报 ›› 1978, Vol. 36 ›› Issue (2): 81-88.    下一篇

论文

有机聚硅氧烷中的dπ-pπ-πCH3共轭能谱计算——二元均杂共轭系能谱

居冠之   

  1. 山东大学化学系
  • 投稿日期:1977-03-12 发布日期:2013-06-03

THE CALCULATION OF dπ-pπ-πCH3 CONJUGATED ENERGY LEVELS OF ORGANIC POLYSILOXANES——ENERGY LEVELS OF BINARY UNIFORM HETERONUCLEI CONJUGATED SYSTEMS

CHU KUAN-CHIH   

  1. Department of Chemistry, Shangtong University
  • Received:1977-03-12 Published:2013-06-03

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本文用“简化的分子轨道理论”,解出了较复杂体系,即聚硅氧烷的单环、直链和链环兼备体系的dπ-pπ-πCH3,共轭能谱的封闭表达式.同时,也揭示了“简化的分子轨道理论”处理二元均杂共轭体系的一般方法.

Closed formulas of dπ-pπ-πCH3 conjugated energy levels for oompleg polyeiloxanes including straight chain, monocyclio and chain-ring systems are formulated employing "simplified molecular orbital theory" developed by us.A general method of "simplified molecular orbital theory" in the treatment of binary uniform heteronuclei conjugated systems is presenied.