化学学报 ›› 1978, Vol. 36 ›› Issue (4): 249-260. 上一篇    下一篇

论文

空气电极渗液和盐析出机理的探讨

陆君涛, 查全性, 严河清, 白力军   

  1. 武汉大学化学系
  • 投稿日期:1977-09-25 发布日期:2013-06-03

ON THE MECHANISM OF WEEPING AND SALTPRECIPITATION OF AIR ELECTRODES

LU CHUN-TAO, CHA CHUAN-SING, YEN HO-CHING, PAI LI-CHUN   

  1. Department of Chemistry, Wuhan University
  • Received:1977-09-25 Published:2013-06-03

实验证明防水型气体电极“冒汗”现象主要是电极内部液压增高所致.根据传质公式推导了储存和放电时电极内部的液流和液压公式,计算结果与实验数据大致相符.根据这一机理,提出防止出现“冒汗”的主要措施应为减小电极内部的液体流动阻力.根据对相图的分析,证明空气电极“冒盐”的必要条件是在电极内部碱液浓缩和碳酸化,并提出解释冒盐过程的“盐塞”机理,能较好地说明实验中观察到的各种冒盐现象.

It is found that the "weeping" of hydrophobic.gas electrodes is caused mainly by the increase of fluid pressure within electrodes.Equations were derived with which liquid flow rate and liquid pressure within electrodes can be calculated.Results of theoretical calculations agree reasonably well with experimental data.Based on suoh mechanism, it is suggested that "weeping" could be preimented effectively by minim izing liquid flow resistance within electrodes.From analysis of phase diagram, it is clear that the concentration and carbonate formation of alkali electrolyte is a prerequisite of salt-precipitation on and within electrodes.The mechanism of "salt-plug" formation was suggested to explain the various aspects of salt-precipitation phenomena observed in experiments.