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化学学报
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化学学报 ›› 1979, Vol. 37 ›› Issue (1): 21-29. 上一篇    下一篇

论文

四种(3,4),(8,9)-双环氧-三环[5.2.1.02,6]癸烷的合成和构型

黄志镗, 韩孝族   

  1. 中国科学院化学研究所
  • 投稿日期:1978-03-20 发布日期:2013-06-03

THE SYNTHESES AND CONFIGURATION OF FOUR(3,4),(8,9) DIEPOXYTRICYCLO-[5.2.1.02,6]DECANE ISOMERS

HUANG CHIH-TANG, HAN HSIAO-TSU   

  1. Institute of Chemistry, Academia Sinica
  • Received:1978-03-20 Published:2013-06-03

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以内式及外式-三环[5.2.1.02,6]癸二烯-3,8为原料进行部分环氧化反应,先制得在[2.2.1]庚烷环上具有环氧基的单氧化物.然后分别以过醋酸环氧化,或进行次氯酸酯加成,继而脱去氯化氢而环氧化,制得四种立体构型不同的(3,4),(8,9)-双环氧-三环[5.2.1.02,6]癸烷.对它们的构型进行了讨论.

Two (8, 9)opogytricyclo[5.2.1.02,6]dec-3-enes were prepared from endoand ego-tricyclo [5.2.1.02,6] dec-3, 8-diene by partial epoxidation.Further epoxidation was carried out separately by oxidation with peracetic acid or by addition with hypoohlorite followed by elimination of hydrogen chloride.Thus four stereoisomers of (3, 4),(8, 9)diepogytrieyclo[5.2.1.02,6] decane were obtained.Their configurations were discussed.