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化学学报
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化学学报 ›› 1979, Vol. 37 ›› Issue (3): 201-206. 上一篇    下一篇

论文

(3,4),(8,9)-双环氧-内式-三环[5.2.1.02,6]癸烷在丙酮溶液中同氯化氢的开环反应

邓先模, 黄志镗   

  1. 中国科学院化学研究所 北京
  • 投稿日期:1978-03-20 发布日期:2013-06-03

THE RING OPENING REACTION OF (3,4), (8,9)-DIEPOXYENDOTRICYCLO [5.2.1.02,6] DECANE WITH HYDROGEN CHLORIDE IN ACETONE

DENG XIAN-MU, HUANG ZHI-TANG   

  1. Institute of Chemistry, Academia Sinica, Beijing
  • Received:1978-03-20 Published:2013-06-03

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研究了(3,4),(8,9)-双环氧-内式-三环[5.2.1.02,6]癸烷及其外式异构体以及若干有关模型化合物在丙酮溶液中同氯化氢的开环反应,证明了其环戊烷环上的环氧基比双环[2.2.1]庚烷环上的环氧基具有较大的活泼性。

Tho rirg opening reaotion of (3, 4),(8, 9)-diepogyendotrioyolo [5.2.1.02,6] decane and its exo-isomer and some related model oomponnds with hydrogen ohloride in acetone was studied.The results indioated that the epoxy group on oyolopentane ring was morn reaotive towards suoh ring opening agent than that on the bioyolo [2.2.1] hoptane ring.