化学学报 ›› 1982, Vol. 40 ›› Issue (9): 790-796. 上一篇    下一篇

论文

巩县风化煤黄腐酸在有机溶剂中溶解机理的研究

王天立, 陈荣峰   

  1. 河南化学研究所 郑州
  • 投稿日期:1981-02-02 发布日期:2013-06-03
  • 通讯作者: 王天立

INVESTIGATION ON THE MECHANISM OF DISSOLUTION OF COAL FULVIC ACID IN ORGANIC SOLVENTS

WANG TIAN-LI, CHEN RONG-FENG   

  1. Henan Research Institute of Chemistry, Zhengzhou
  • Received:1981-02-02 Published:2013-06-03

为考察风化煤黄腐酸(FA)的溶解机理,提出了一个溶剂体系。通过对巩县风化煤FA溶解能力实验和分级溶解,发现溶剂对FA的溶解能力取决于溶剂形成氢键能力的溶解度参数δa,即FA的溶解度随δa值的增加而增加。用化学分析,IR,13C NMR谱对各级分进行结构表征,结果表明:芳香度、醌基含量等呈现出的规律性变化与形成氢键为主导因素的溶解机理相一致。

A series of solvents is suggested for studying the dissolution mechanism of the fulvic acid from Gongxian weathered coal.It has been found that the solubilities of the fulvic acid in different organic solvents depend mainly on the solvent's parameter δa,which represents the hydrogen bonding ability of the solvem i.e.the solubility of the coal fulvie acid increases with the δa value of the solvent.These fractions separated by various solvents have been ehararcterized by elemental and functional group analyses.1R.a.nd 13C NMR.The results show that the regular changes of aromatioity and quinonoie contents in different fractions a.re in agreement with the proposed dissolution mechanism in which tho formation of hydrogen bonding is regarded as the leading factor in di}sulution.