化学学报 ›› 1983, Vol. 41 ›› Issue (3): 284-288. 上一篇    

研究论文

溶解度法研究铑(III)与亚硝酸根的配合作用

章健民;杨丙雨;何振宇;马光甲   

  1. 徐州稀贵金属研究所
  • 发布日期:1983-03-15

A study of complexes of Rh(III) with nitrite ions by solubility method

ZHANG JIANMIN;YANG BINGYU;HE ZHENYU;MA GUANGJIA   

  • Published:1983-03-15

关键词: 溶解度, 亚硝酸根络合物, 络合物化学, 铑络合物

The complexation of Rh(III) with nitrite ions was studied at ionic strength 3.0 and at 16`,26` and 35`C by solubility method. The results showed the formation of 1:1, 1:2, 1:3, 1:4, 1:5 and 1:6 complexes of Rh(III) with nitrite ions. The consecutive stability constants a1.d thermodynamic parameters ΔG0, ΔH and ΔS0 of complexation were calculated from the experimental data.

Key words: SOLUBILITY, NITRITO COMPLEX, COORDINATE CHEMISTRY, RHODIUM COMPLEX

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