化学学报 ›› 1983, Vol. 41 ›› Issue (5): 397-402. 上一篇    下一篇

研究论文

关于分子介质中三重态正子素(O-Ps)寿命 τ3的探讨

张曼维;张志成   

  1. 中国科学技术大学近代化学系
  • 发布日期:1983-05-15

On lifetime of ortho-positronium (o-Ps) in molecular substances

ZHANG MANWEI;ZHANG ZHICHENG   

  • Published:1983-05-15

关键词: 正电子, 湮灭, 猝灭效应, 介电性质, 电子偶素

In this paper the lifetime of o-Ps is discussed. It is considered that the lifetime of o-Ps in condensed molecular substances depends primarily on the volume-factors and dielectric properties of materials, but the chemical and paramagnetic quenching of o-Ps by molecules and active radicals created in the spur can not be neglected, and sometimes they affect the lifetime of o-Ps considerably. A semi-empiricial formula for estimation of lifetime of o-Ps in pick-off annihilation is proposed, it is expressed as: \I\3 = K(M\I\/\T\-\S\Voi)/e\S\Zi where K=3.08(ns/cm3) is an empirical constant; s e is the dielectric constant of material; Mr and \T\ are the molecular weight and density of material respectively; Zi and Voi are the number of valence electrons and the mole excluded volume, respectively, of atom i by which the molecules of material are constituted. An empirical formula for Voi is also proposed. By comparison between calculated and experimental \I\3 values, a discussion about the influence of the free radicals in the spur and molecules of material on o-Ps lifetime is made.

Key words: POSITRONS, ANNIHILATIONS, QUENCHING EFFECTS, DIELECTRIC PROPERTY, POSITRONIUM

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