化学学报 ›› 1983, Vol. 41 ›› Issue (7): 577-584.    下一篇

研究论文

苯甲酰基五氟丙酰基亚甲基三苯基胂的晶体和分子结构

夏宗芗;张志明   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1983-07-15

The crystal and molecular structure of benzoylpentafluoropropionymethylene triphenylarsorane

XIA ZONGXIANG;ZHANG ZHIMING   

  • Published:1983-07-15

关键词: 晶体结构测定, 丙酸 P, X射线衍射分析, 苯甲酸 P, 三苯基, 有机氟化合物, 重原子法, 胂, 内翁盐

Benzoylpentafluoropropionylmethylene triphenylarsorane contains two strongly electron-withdrawing groups in methylene moiety. Single crystals obtained from CH3OH-H2O solution are triclinic, the space group is P1. The X-ray diffraction intensity data were collected by a four-circule diffractometer. The structure has been solved by the heavy-atom method and refined by the block-diagonal least-squares method.

Key words: CRYSTAL STRUCTURE DETERMINATION, METHYLACETIC ACID P, X-RAY DIFFRACTION ANALYSIS, BENZENECARBOXYLIC ACID P, TRIPHENYL GROUP, ORGANO FLUORINE COMPOUNDS, HEARY ATOM TECHNIQUE (METHOD), ARSINE, YLIDE

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