化学学报 ›› 1987, Vol. 45 ›› Issue (12): 1163-1169. 上一篇    下一篇

研究论文

平面电极上分支加和循环伏安法的研究

赵平三;漆德瑶   

  1. 上海工业大学化学化工系
  • 发布日期:1987-12-15

Study on branch addition cyclic voltammetry at planar electrode

ZHAO PINGSAN;QI DEYAO   

  • Published:1987-12-15

本文用固定电极电容电流理论对分支加和循环伏安法消除电容电流影响的原理作了说明;用数值模拟解法导出了平面电极可逆、准可逆和不可逆过程的理论方程;对其中的可逆过程作了实验验证.理论与实验结果一致.

关键词: 定量分析, 数值模拟, 循环伏安法, 加和效应, 边值控制, 平面电极

The theories of branch addition cyclic voltammetry for reversible, quasi-reversible and irreversible processes at the planar electrode were deduced with the digital simulation method. The principle of eliminating the charging current by this method was described. The theory for reversible process was verified by experiments

Key words: QUANTITATIVE ANALYSIS, NUMERICAL SIMULATION, CYCLOVOLTAMGRAPH, ADDITIVE EFFECT, BOUNDARY VALUE CONTROL, PLANAR ELECTRODE

中图分类号: