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化学学报 ›› 1987, Vol. 45 ›› Issue (12): 1175-1179. 上一篇 下一篇
研究论文
黄维垣;钱昭辉
发布日期:
HUANG WEIYUAN;QIAN ZHAOHUI
Published:
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A本文报道了三个含氟天麻素及其衍生物的合成,即2-氟-4-羟甲苯基-β-D-葡萄吡喃糖苷,2-三氟甲基-4-羟甲苯基-β-D-葡萄吡喃糖苷,2,3,5,6-四氟-4-羟甲苯基-β-D-葡萄吡喃糖苷及其五乙酰衍生物等.这些新化合物的结构经元素分析,^1H和^1^9F NMR,IR,和MS等测试确证.
关键词: 天麻, 红外分光光度法, 元素分析, 质谱法, 核磁共振谱法, 吡喃糖, 葡萄糖, 质子磁共振谱法, 糖苷, 结构分析
The synthesis of several fluorinated derivatives of gastrodin (I) was described. These compounds are 2-fluoro-4-hydroxymethylphenyl-b-D-glucopyranoside, 2-trifluoromethyl-4-hydroxymethylphenyl-b-D-glucopyranoside, 2,3,5,6-tetrafluoro-4-hydroxymethylphenyl-b-D-glucopyranoside and their pentaacetyl derivatives
Key words: GASTRODIA ELATA, INFRARED SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, MASS SPECTROGRAPHY, NMR SPECTROMETRY, PYRANOSE, GLUCOSE, PROTON MAGNETIC RESONANCE SPECTROMETRY, GLYCOSIDE, STRUCTURAL ANALYSIS
中图分类号:
O629
黄维垣,钱昭辉. 含氟天麻素的合成[J]. 化学学报, 1987, 45(12): 1175-1179.
HUANG WEIYUAN;QIAN ZHAOHUI. The synthesis of fluorinated gastrodin[J]. Acta Chimica Sinica, 1987, 45(12): 1175-1179.
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