化学学报 ›› 1987, Vol. 45 ›› Issue (2): 198-200. 上一篇    下一篇

研究论文

氯苯硝化副产物的研究: 氯代三硝基二苯胺的分离与结构

曾盛德;马长清   

  1. 武汉医学院药学系
  • 发布日期:1987-02-15

Study of the byproducts from the nitration of chlorobenzene: Isolation and structures of chloro-trinitro-diphenylamines

ZENG SHENGDE;MA CHANGQING   

  • Published:1987-02-15

从氯苯硝化母液中用薄层色谱分离到二个新的氯代三硝基二苯胺.用UV,IR,NMR,MS和一些物理化学数据的测定推导出它们的结构为4-氯-2',3',6'-三硝基二苯胺和4-氯-2',3',4'-三硝基二苯胺.

关键词: 薄层色谱, 紫外分光光度法, 硝基化合物, 苯胺 P, 红外分光光度法, 核磁共振谱法, 结构分析, 氯苯 P, 硝基化

Chlorotrinitrodiphenylamines I (R1, R2 = H, NO2; NO2, H) were isolated by TLC as byproducts from nitration of chlorobenzene.

Key words: THIN-LAYER CHROMATORGAPHY, ULTRAVIOLET SPECTROPHOTOMETRY, NITRO COMPOUNDS, BENZAMINE P, INFRARED SPECTROPHOTOMETRY, NMR SPECTROMETRY, STRUCTURAL ANALYSIS, CHLOROBENZENE P, NITRATION

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