化学学报 ›› 1988, Vol. 46 ›› Issue (1): 26-29. 上一篇    下一篇

研究论文

中国乌头的研究 XXII: 赣烷乌头生物碱的研究

蒋山好;洪山海;宋宝珠;朱元龙;周炳南   

  1. 中国科学院上海药物研究所;上海中医学院附属龙华医院;上海中医研究所
  • 发布日期:1988-01-15

Studies on the Chinese drug, aconitum spp. XXII: Alkaloids from aconitum finetianum Hand-Mazz

JIANG SHANHAO;HONG SHANHAIAI;SONG BAOZHU;ZHU YUANLONG;ZHOU BINGNAN   

  • Published:1988-01-15

从赣皖乌头(Aconitum finetianum Hand-Mazz)中又分得五个生物碱, 其中三个为新的二萜类生物碱, 分别命名为去氧刺乌头碱(deoxylappaconitine), 赣乌新碱(neofinaconitine)和异刺乌状碱(isolappaconitine), 经IR、MS、^1H和^1^3C NMR推定了它们的化学结构, 另两个为已知生物碱ajacine和inuline.

关键词: 红外分光光度法, 质谱法, 碳13核磁共振谱法, 质子磁共振谱法, 乌头属, 二萜烯生物碱

Three new alkaloids, 9-deoxylappaconitine, (I), neofinaconitine (II), isolappaconitine (III), and two known alkaloids, adjacine and inuline, were isolated from the root of A. finetianum. Their chem. structures were established by IR, 1H and 13C NMR, and mass spectral data and chem. evidences.

Key words: INFRARED SPECTROPHOTOMETRY, MASS SPECTROGRAPHY, C13 NMR SPECTROMETRY, PROTON MAGNETIC RESONANCE SPECTROMETRY, ACONITUM, DITERPENE ALKALOID

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