关键词: 特性粘数, 分子量, 聚苯乙烯, 粘度法, 膜法, 渗透压, 分子链构象

The no.-av. mol. wt. (M), second virial coefficients A2, and intrinsic viscosity [h] of short-chain polystyrene (I) were measured by dynamic membrane osmometry and viscometry. The [h]-M relations for I (2.5 ?103 < M < 1.5 ?104) in PhMe, CHCl3, and acetone were close to one another, and in agreement with the literature data for I in cyclohexane at 34.5? which was represented as [h] = 8.8 ?10-2 M0.50. The value of A2 increased rapidly with decreasing M. The osmotic pressure results combined with literature data yielded A2os= KM-1.6, and A2oswas always higher than that from light scattering. The mean square radius of gyration, end-to-end distance, and expansion factor calculated from viscosity values according to Flory viscosity theory and the Stockmayer-Fixman equation were consistent with the literature. The results implied that in the region of M from 400 to 1.5 ?104 for I, there was a transition from small mol. to macromol., and the short-chain I in dilute solution existed as a wormlike chain.

Key words: INTRINSIC VISCOSITY, MOLECULAR WEIGHT, POLYSTYRENE, VISCOMETRY, MEMBRANE PROCESS, OSMOTIC PRESSURE, MOLECULAR CHAIN COMFORMATION