化学学报 ›› 1992, Vol. 50 ›› Issue (3): 294-299. 上一篇    下一篇

研究论文

三[(苯基二甲硅基)亚甲基]锡 O,O-二芳基二硫代磷酸酯的研究

谢庆兰;罗宁;李靖;荆煦英   

  1. 南开大学元素有机化学研究所
  • 发布日期:1992-03-15

Studies of tri[(dimethylphenylsilyl)methylene]tin o,o-diaryldithiophosphates

XIE QINGLAN;LUO NING;LI JING;JING XUYING   

  • Published:1992-03-15

本文合成了十五个新的[苯基二甲硅基]锡O,O-二芳基二硫代磷酸酯。测定了它们的IR, ^1H, ^1^3C, ^1^1^9Sn NMR及MS, ^1^1^9Sn NMR的化学位移δ和芳环对位取代基的Hammett常数σ之间存在良好的线性关系。

关键词: 红外分光光度法, 分子结构, 质谱法, 核磁共振谱法, 结构分析, 有机硅化合物, 有机锡化合物, 二硫代磷酸酯, HAMMETT常数

Fifteen new title compounds, e.g., (PhMe2SiCH2)3SnSP(S)(OPh)2, were synthesized and characterized by IR, 1H, 13C, 119Sn NMR, mass spectrometry and elemental anal. These compounds contain a tetracoordinated Sn atom. A good linear relationship was found between the 119Sn chem. shifts and the para-substituted Hammett constant (s).

Key words: INFRARED SPECTROPHOTOMETRY, MOLECULAR STRUCTURE, MASS SPECTROGRAPHY, NMR SPECTROMETRY, STRUCTURAL ANALYSIS, ORGANO SILICON COMPOUNDS, ORGANO TIN COMPOUNDS, PHOSPHORDITHIOATE

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