化学学报 ›› 1994, Vol. 52 ›› Issue (2): 181-185. 上一篇    下一篇

研究论文

微环电极上线性扫描伏安法准稳态可逆波理论

金葆康;张祖训   

  1. 南京大学化学系
  • 发布日期:1994-02-15

The theory of linear sweep voltammetry for the quasi-steady-state reversible wave at ultramicroring electrode

JIN BAOKANG;ZHANG ZUXUN   

  • Published:1994-02-15

本文求得了适用于不同γ(式(6))和P(式(9))的最大电流表达式,并提出了准稳态的定量标准,还推导了微环电极上线性扫描伏安法准稳态可逆波方程式,经验证,理论和实验结果相符合

关键词: 伏安法, 电化学反应, 亚稳态, 微电极

The expression of the max. current variation with g and P at ultramicroring electrode for linear sweep voltammetry is presented, the rule of judgement for the quasi-steady-state reversible wave is described, and the equation of linear sweep voltammetry for the quasi-steady-state reversible wave is derived also. Experimental results are in good agreement with the theor.6

Key words: VOLTAMMETRY, ELECTROCHEMICAL REACTION, METASTABLE STATES, MICROELECTRODE

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