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化学学报
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化学学报 ›› 1994, Vol. 52 ›› Issue (5): 517-520. 上一篇    

研究论文

臭灵丹化学成分研究II

赵爱华;魏均娴   

  1. 昆明医学院天然药物化学研究室
  • 发布日期:1994-05-15

Studies on the constituent of decoctum of Laggera Pterodonta (DC) benth II.

Zhao Aihua;Wei Junxian   

  • Published:1994-05-15

PDF

437

被引次数

27

从臭灵丹(LaggeraPterodonta(DC)Benth)地上部分水煎浓缩液的氯仿提取液中,分离出四个化合物(1-4),1和2为倍半萜化合物,3和4为黄酮化合物,经紫外光谱、红外光谱、核磁共振^1H谱、^1^3C谱、^1H-^1Hcosy谱及质谱测定,分别为臭灵丹酮酸、冬青酸、洋艾素和金腰素乙。化合物1具有桉烷型倍半萜结构,为Δ^4^,^1^1-桉双烯-3-酮-13-酸,它是一新化合物。

关键词: 化学成分, 臭灵丹, 紫外分光光度法, 黄酮类化合物, 倍半萜, 红外分光光度法, 核磁共振, 质谱法, 冬青酸, 洋艾素

From the chloroform extract of decoctum of Laggera Pterodonta (DC) Benth (Compositae) aried part, Compound 1-4 were obtained after colum chromatography on silical gel and crystallization. 1 is a new compound which has sesquiterpene skeleton of eudesmane based on ^1^3C NMR, ^1H-^1H cosy and mass spectral data. It has the structure of Δ ^4^,^1^1-eudesm-dien-3-one-13-oic acid. 2-4 were elucidated as the known ilicic acid, artemitin and chrysospeneti B respectively based on the spectroscopic data and comparision with the literature.

Key words: CHEMICAL COMPOSITION, ULTRAVIOLET SPECTROPHOTOMETRY, FLAVONOID, SESQUITERPENE, INFRARED SPECTROPHOTOMETRY, NUCLEAR MAGNETIC RESONANCE, MASS SPECTROGRAPHY

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