化学学报 ›› 1995, Vol. 53 ›› Issue (1): 26-30. 上一篇    下一篇

研究论文

固相配位化学反应研究 LⅨ.反应截面移动法研究氢氧化铜与α-alaH的固相反应

景苏;忻新泉   

  1. 南京大学化学系;南京大学国家配位化学重点实验室
  • 发布日期:1995-01-15

Studies on the solid state reaction of coordination compounds LⅨ.Investigation of solid state reaction of cu(OH)~2 and α-alaH by intersection face moving method

JING SU;XIN XINQUAN   

  • Published:1995-01-15

本文提出用反应截面法研究氢氧化铜和α-alaH的室温固相反应,讨论了反应温度及表面状态等影响截面移动的因素, 对表面反应速度的决定因素进行了讨论并计算了反应活化能.

关键词: 丙氨酸, 活化能, 反应速度, 固相反应, 氢氧化铜, 截面移动法

Intersection face moving method is designed to study the solid state reaction of Cu(OH)2 and a-alaH at room temperature The influence of reaction temperature, molar ratio and surface condition are investigated. In this system, the interface chem. reaction is the rate determine step of the apparent reaction, and the activation energy is calculated as 39.8 kJ.mol-1.

Key words: ALANINE, ACTIVATION ENERGY, REACTION RATE, SOLID PHASE REACTION, CUPRIC HYDROXIDE

中图分类号: