化学学报 ›› 1996, Vol. 54 ›› Issue (5): 481-486. 上一篇    下一篇

研究论文

相似分析/质谱法鉴别二十种脂肪族双烯-1-醇及乙酸酯

袁谷;何美玉;贺晓然   

  1. 北京大学化学系
  • 发布日期:1996-05-15

Identification of aliphatic dienic alcohols and acetates by fuzzy similarity analysis/mass spectrometry

YUAN GU;HE MEIYU;HE XIAORAN   

  • Published:1996-05-15

本文报道了二十个脂肪族双烯-1-醇和乙酸酯EI-质谱的特征, 并提出了相似分析法鉴别这些共轭双烯、孤立双烯的双键位置及几何异构体的质谱。

关键词: 乙酸酯, 质谱法, 异构体, 烯醇, 昆虫性信息素

In this paper, a procedure is presented for identification of dienic alcohols and acetates by the comprehensively analyzing similarity of the mass spectral patterns of these isomers. The method was tested with spectra of twenty straight-chain dienic alcohols and acetates, each spectrum was distinguished unambiguously in all runs without prior chemical modification.

Key words: ACETIC ACID ESTER, MASS SPECTROGRAPHY, ISOMER, ENOLS

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