化学学报 ›› 1999, Vol. 57 ›› Issue (5): 453-457. 上一篇    下一篇

研究论文

低能氮离子对苯甲酸钠溶液的化学改性

韩建伟;王相勤;余增亮   

  1. 中国科学院等离子体物理研究所.合肥(230031)
  • 发布日期:1999-05-15

Chemical modification of PhCOONa solution by low-energy nitrogen ions

Han Jianwei;Wang Xiangqin;Yu Zengliang   

  1. Inst of Plasma Phys, CAS.Hefei(230031)
  • Published:1999-05-15

利用气体尖端放电产生低能氮离子,这些离子在放电间隙的电场加速下攻击苯甲酸钠(PhCOONa)水溶液,造成溶液中分子的损伤。氮离子的作用使溶液的紫外吸收发生显著的变化,与茚三酮呈正反应,表明进入溶液的氮元素形成了某种形式的氨基。红外吸收光谱的分析进一步表明低能氮离子与PhCOONa溶液作用形成了酰胺及亚硝基化合物。所有的实验结果都反映了低能离子通过损伤分子及进一步与损伤碎片化学合成的化学改性作用。

关键词: 苯甲酸P, 化学改性, 氮离子, 茚三酮, 红外分光光度法

Low-energy nitrogen ions were produced with gas point discharge, and the ions were accelerated directly by the potential degradation above the cathode into PhCOONa solution. The induced change for UV absorption was measured. After the nitrogen ions impact, PhCOONa solution showed positive reaction with ninhydrin, which indicated that some types of amino group were formed when the nitrogen ions attack the solution. The investigation of infrared spectra further demonstrated that amide and nitroso-compound were the damage products. In general, the present paper clearly demonstrates the chemical modification effects of low energy ions on substances in solution.

Key words: BENZENECARBOXYLIC ACID P, CHEMICAL MODIFICATION, NITROGEN ION, NINHYDRIN, INFRARED SPECTROPHOTOMETRY

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