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化学学报
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化学学报 ›› 2001, Vol. 59 ›› Issue (5): 729-735. 上一篇    下一篇

研究论文

一维链状冠醚配合物[k(18-C-6)]~2[M(NO~2)~4](H~2O)(M=Pd,Pt) 的合成与结构

窦建民;宋兴民;刘颖1;李雪;郑培菊;杜晨霞;朱玉   

  1. 山东省聊城师范学院化学系;复旦大学分析测试中心.上海(200433);郑州大学 应用化学重点实验室
  • 发布日期:2001-05-15

One -dimensional chain complexes: Syntheses and crystal structures of [k(18-C-6)]~2[M(NO~2)~4](H~2O)(M=Pd,Pt)

Dou Jianmin;Song Xingmin;Liu Ying;Li Xue;Zheng Peiju;Du Chenxia;Zhu Yu   

  1. Fudan Univ, Ctr Anal & Measurement.Shanghai(200433)
  • Published:2001-05-15

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研究了18-C-6分别与k~2[Pd(NO~2~4],k~2[Pt(NO~2)~4])的反应，并通过元素分析、红外光谱、单晶X射线衍射对生成的配合物[k(18-C-6)]~2[Pd(NO~2)~4](H~2O)~0.5(1)和[k(18-C-6)]~2,k~2[Pt(NO~2)~4])(H~2O)(2)进行了表征，两个配合匀匀为单斜晶系，空间P2~1/c.1的晶体学数据：α=1,7104(3),c=1,5763(3)nm,β=93.49(3)°,V=3.9987(14)nm^3,Z=4,D~c=1.507g/cm^3,F(000)=1880,R~1=0.0681,~wR~2=0.1004。2的晶体学数据：a=1.1312(3)nm,b=1.4227(2)nm,c=1.2266(3)nm,β93.141(10)°,V=1.9711(8)nm^3,Z=4,D~c=1.614g/cm^3,F(000)=936,R~1=0.0265,~wR~2=0.0721。在固态，配合物1具有[(18-c-6)]~2[Pd(NO~2)~4](H~2O)(1a)和[(18---c-6)]~2[Pd·(NO~2)~4](1b)两个分子，两者比例这1：1前者相邻的两个分子通过水分是的氧原子相连接形成一维链状结构，后者形面假一维链状结构，在配合物2中相邻的两个分子通过品分子中的氧原子相连接形成一维链状结构。

关键词: 冠醚, 晶体生长, 元素分析, 红外分光光度法, Ｘ射线衍射分析, 钯络合物, 铂络合物

The reactions of 18-crown-6 with [k(18-C-6)]~2[M(NO~2)~4] (H~2O) (M=Pd,Pt) were studied and the complex k(18-C-6)]~2 [Pd(no~2)~4](H~2o) ~0.5(1) and complex [k(18-C-6)]~2,k~2[Pt(NO~2)~4]) (H~2O)(2)were characterized by X -ray diffraction analysis. Two complexes belong to monoclinic, group P2~1/c with cell dimensions, 1α=1,7104(3),c=1,5763 (3)nm ,β=93.49(3)°, V=3.9987(14)nm^3, Z =4, D~c=1.507g/cm^3, F(000) =1880,R~1=0.0681, ~wR~2=0.1004 and 2: a=1.1312(3)nm, b=1.4227(2)nm, c=1.2266(3)nm, β93.141(10)°,V= 1.9711(8)nm^3, Z=4, D~c=1.614g/cm^3, F(000)=936, R~1=0.0265, ~w R~2=0.0721.In the solid state, complex 1 contains two molecules :[(18-c-6)]~2[Pd(NO~2)~4](H~2O)(1a) and[(18-c- 6)]~2[Pd·(NO~2)~4] (1b).The former has a one --dimensional chain containing two [k(18- C-6)]^+complex cations a [Pd(NO~2)~4]^2- anion hridged by one H~2O molecule between the adjacent [k(18-C-6)]^+ units. Complex 2 also has a one -dimensional chain consisting of two [k(18-C-6)]^+ complex cations and a[Pd(NO~2)~4]^2 anion bridged by one H~2O molecule between the adjacent [k(18-C-6)]^+untis.

Key words: CROWN ETHER, CRYSTAL GROWTH, ELEMENTAL ANALYSIS, INFRARED SPECTROPHOTOMETRY, X-RAY DIFFRACTION ANALYSIS, PALLADIUM COMPLEX, PLATINUM COMPLEX

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