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化学学报
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化学学报 ›› 2001, Vol. 59 ›› Issue (9): 1513-1518. 上一篇    下一篇

研究论文

多吡啶钌(Ⅱ)配合物化学发光性质研究

韩鹤友;何治柯;曾云鹗   

  1. 中国科学技术大学化学系.合肥(230026);武汉大学化学系.武汉(430072)
  • 发布日期:2001-09-15

Study on the chemiluminescent characteristics of mulitbipyridine ruthenium (Ⅱ) complexes

Han Heyou;He Zhike;Zeng Yune   

  1. Univ Sci & Technol China, Dept Chem.Hefei(230026);Wuhan Univ, Dept Chem.Wuhan(430072)
  • Published:2001-09-15

PDF

1031

被引次数

8

详细研究了Ru(bpy)3^2+,Ru(bpy)2(dppx)^2+,Ru(bpy)2(dppz)^2+,Ru(phen)3^2+,Ru(phen)2(dppx)^2+和Ru(phen)2(dppz)^2+六个多吡啶钌(Ⅱ)配合物的化学发光性质，筛选出Ru(bpy)3^2+和Ru(phen)3^2+两种性能优良的化学发光试剂；并探讨了它们发光的可能机理和影响因素，为钌(Ⅱ)配合物在化学发光分析中的应用提供了可供参考的理论依据。

关键词: 化学发光, 钌络合物, 吡啶P, 二氮杂菲, 硫酸铈

The chemiluminescent characteristics of Ru(bpy)3^2+, Ru(bpy)2(dppx) ^2+, Ru(bpy)2(dppz)^2+, Ru(phen)3^2+, Ru(phen)2(dppx)^2+ and Ru(phen)2 (dppz)^2+ have been studied in detail. It is found that Ru(bpy)3^2+ and Ru(phen)3^2+ have better chemiluminescence activities than others. A mechanism of luminescence of these ruthenium complexes is proposed. The results obtained may be useful as theory references for applications of ruthenium (Ⅱ) complexes in many chemiluminescence systems.

Key words: CHEMILUMINESSENCE, RUTHENIUM COMPLEX, PYRIDINE P, PHENANTHROLINE

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