化学学报 ›› 2004, Vol. 62 ›› Issue (19): 1935-1940. 上一篇 下一篇
研究论文
夏忠庭1, 刘大有1, 王晓颖1, 刘科峰1, 张培成2
XIA Zhong-Ting1, LIU Da-You1, WANG Xiao-Ying1, LIU Ke-Feng1, ZHANG Pei-Cheng2
采用硅胶柱色谱和高效液相色谱等方法,对两头尖的化学成分进行了研究,从中分离得到两个化合物,经化学及IR,ESI-MS,1H NMR,13C NMR,DEPT,HMOC,HMBC,GCOSY,TOCSY等谱学分析鉴定其结构分别为:3-O-α-L-arabinopyranosyl(1 → 3)-α-L-rhamnopyranosyl (1 → 2) [ β-D-glucopyranosyl (1 → 4) ]-α-L-arabinopyranosyl oleanolic acid 28-O-α-L-rhamnopyranosyl (1→4)-β-D-glucopyranosyl(1→6)-β-D-glucopyranoside (1), 3-O-β-D-glucopyranosyl(1→4)-β-D-glucopyranosyl(1→3)-α-L-rhamnopyranosyl(1→2)-α-L-arabinopyranosyl oleanolic acid 28-O-α-L-rhamnopyranosyl(1→4)-β-D-glucopyranosyl(1→6)-β-D-glucopyranoside(2),该两个化合物为新化合物,分别命名为:多被银莲花皂苷16(Raddeanoside 16)和多被银莲花皂苷17(Raddeanoside 17).