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化学学报
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化学学报 ›› 2004, Vol. 62 ›› Issue (20): 2113-2117. 上一篇    下一篇

研究简报

含8-羟基喹啉铝配合物的高分子聚合物的合成与表征

梅群波1,2, 杜乃婴1,2, 吕满庚1   

  1. 1. 中国科学院广州化学研究所, 广东省电子有机聚合物材料重点实验室, 广州, 510650;
    2. 中国科学院研究生院, 北京, 100039
  • 投稿日期:2004-04-16 修回日期:2004-06-30 发布日期:2014-02-17
  • 通讯作者: 吕满庚,E-mail:mglu@gic.ac.cn. E-mail:mglu@gic.ac.cn.
  • 基金资助:
    中国科学院"百人计划"资助项目.

Synthesis and Characterization of High Molecular Weight Polymer Containing Tris(8-hydroxyquinoline)Aluminum(III)Complexes

MEI Qun-Bo1,2, DU Nai-Ying1,2, LÜ Man-Geng1   

  1. 1. Guangdong Key Laboratory of Polymer Materials for Electronics, Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650;
    2. Graduate School of the Chinese Academy of Sciences, Beijing 100039
  • Received:2004-04-16 Revised:2004-06-30 Published:2014-02-17

PDF

408

被引次数

70

通过甲基丙烯酸甲酯(MMA)和含有8-羟基喹啉的单体共聚合成模板聚合物,再与二配体的8-羟基喹啉铝配合物(AlO2)配位,实现了8-羟基喹啉铝配合物的高分子化,获得了一种高分子量金属配合物发光聚合物,并利用元素分析,FTIR,UV,PL光谱,GPC等方法对其结构和性能作了表征.

关键词: 8-羟基喹啉铝配合物, 高分子电致发光器件, 甲基丙烯酸甲酯, 聚合物合成

A new method to synthesize tris(8-hydroxyquinoline)aluminum(AlQ3)-containing polymer was reported. A model polymer containing 8-hydroxyquinoline ligands was obtained by free-radical copolymerization with methyl methacrylate(MMA).High molecular weight polymer-aluminum complexes were prepared by coordinating reaction of model polymer with di(8-hydroxyquinoline)aluminum(AlQ2)chelates.Their structures were confirmed by NMR,FTIR,UV-vis,photoluminescence spectrum,and gel permeation chromatography analysis.

Key words: tris(8-hydroxyquinoline)aluminum complex, polymer light emitting diode(PLED), methyl methacrylate, polymer synthesis