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化学学报
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化学学报 ›› 2008, Vol. 66 ›› Issue (14): 1753-1757. 上一篇    下一篇

研究简报

2-甲基-2-丁烯二酸单甲酯的合成及其与丙烯腈二元共聚的 表观竞聚率的测定

杨俊锋a,b 陆国林*,a 谭久青a 黄晓宇a 陈惠芳c 潘 鼎*,c   

  1. (a中国科学院上海有机化学研究所 上海 200032)
    (b郑州大学化学系 郑州 450001)
    (c东华大学材料科学与工程学院 上海 201620)
  • 投稿日期:2008-06-06 修回日期:2008-06-26 发布日期:2008-07-28
  • 通讯作者: 陆国林

Synthesis of (Z)-2-Methyl-2-Butenedioic Acid-1-Methyl Ester and Determination of Apparent Reactivity Ratio of Copolymerization with Acrylonitrile

YANG, Jun-Feng a,b LU, Guo-Lin *,a TAN, Jiu-Qing a HUANG, Xiao-Yu a
CHEN, Hui-Fang c PAN, Ding *,c   

  1. (a Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032)
    (b Department of Chemistry, Zhengzhou University, Zhengzhou 450001)
    (c College of Material Science & Engineering, Donghua University, Shanghai 201620)
  • Received:2008-06-06 Revised:2008-06-26 Published:2008-07-28
  • Contact: LU, Guo-Lin

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912

被引次数

14 | 2

以柠糠酸酐为原料, 合成了一种可以与丙烯腈(AN, acrylonitrile)共聚的新单体: 2-甲基-2-丁烯二酸单甲酯(MBAME). 以偶氮二异丁腈(AIBN, 2,2’-azobis isobutyronitrile)为引发剂, 70 ℃下引发MBAME与AN在N,N-二甲基甲酰胺(DMF, N,N-dimethylformamide)中进行无规共聚, 通过Fineman-Ross法测定了两者在DMF溶液聚合体系的表观竞聚率, γ1(AN)＝7.985, γ2(MBAME)＝0.599, 有助于优化聚丙烯腈基碳纤维用树脂的生产工艺.

关键词: 甲基丁烯二酸单酯, 丙烯腈, 共聚合, 竞聚率

A new methacrylate monomer, (Z)-2-methyl-2-butenedioic acid-1-methyl ester (MBAME), was synthesized using citraconic anhydride as starting material. This monomer can copolymerize with acrylonitrile in N,N-dimethylformamide at 70 ℃ using 2,2’-azobisisobutyronitrile as initiator. The apparent reactivity ratio of AN/MBAME copolymerization system calculated by Fineman-Ross method was 7.985 for AN and 0.599 for MBAME, respectively. This result may benefit the production of PAN-based carbon fiber.

Key words: (Z)-2-methyl-2-butenedioic acid-1-methyl ester, acrylonitrile, copolymerization, reactivity ratio