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化学学报
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化学学报 ›› 2008, Vol. 66 ›› Issue (17): 1979-1984. 上一篇    下一篇

研究论文

精氨酸插层氧化锰纳米结构材料的制备和表征

周 青 张成孝 刘宗怀* 唐秀花

  

  1. (应用表面与胶体化学教育部重点实验室 西安 710062; 陕西师范大学化学与材料科学学院 西安 710062)

  • 投稿日期:2008-01-21 修回日期:2008-03-13 发布日期:2008-09-14
  • 通讯作者: 刘宗怀

Preparation and Characterization of Arginine Intercalated Layered Manganese Oxide Nanocomposite

ZHOU, Qing ZHANG, Cheng-Xiao LIU, Zong-Huai* TANG, Xiu-HuaQing zhou   

  1. (Key Laboratory of Applied Surface and Colloid Chemistry (Shaanxi Normal University), Ministry of Education, Xi’an 710062, School of Chemistry and Materials Science, Shaanxi Normal University, Xi’an 710062)
  • Received:2008-01-21 Revised:2008-03-13 Published:2008-09-14
  • Contact: LIU, Zong-Huai

PDF

1694

被引次数

14 | 4

应用氧化法水热合成了Na型层状氧化锰[BirMO(Na)], 通过离子交换反应在0.1 mol/L HCl溶液中Na型层状氧化锰转化成H型层状氧化锰[BirMO(H)]. BirMO(H)在四甲基氢氧化铵[(CH3)4NOH]溶液中搅拌处理7 d后, 剥离生成了MnO2纳米层胶体分散液. 剥离的MnO2纳米层胶体分散液在pH＝4.0～11.0的精氨酸溶液中搅拌2 d, 得到了层间距为1.49 nm的精氨酸插层氧化锰纳米结构材料. 通过XRD, DSC-TGA, SEM, IR及元素分析对合成试样进行了分析表征. 结果表明精氨酸在氧化锰层间的插入量及插入形式与重组溶液的pH值密切相关, 其最大插入量为1.80 mmol/g.

关键词: 层状氧化锰, 插入, 精氨酸, 剥离/重组, 纳米结构

Na-type layered manganese oxide [BirMO(Na)] was hydrothermally prepared by a oxidation method, then it was translated into H-type layered manganese oxide [BirMO(H)] in a 0.1 mol/L HCl solution. When BirMO(H) was treated in a (CH3)4NOH solution for 7 d, it was delaminated into MnO2 nanosheet colloid suspension. The MnO2 nanosheet colloid suspension was poured into an arginine solution of pH＝4.0～11.0 followed by stirring for 2 d, then arginine intercalated layered manganese oxide nanocomposite with a basal spacing of 1.49 nm (ARILMO) was prepared by a delamination/reassembling process. The obtained ARILMO sample was characterized by XRD, DSC-TGA, SEM, IR and elemental analysis. Experimental results indicated that the intercalated type and the amount of arginine molecules were connected with the pH values of the arginine solutions, and the intercalated amount of arginine molecules was 1.80 mmol/g.

Key words: layered manganese oxide, intercalation arginine, delamination/reassembling, nanocomposite