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化学学报
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化学学报 ›› 1992, Vol. 50 ›› Issue (5): 473-478. 上一篇    下一篇

研究论文

2-羟基-3-甲氧基苯甲醛与α-萘胺Schiff碱硝酸稀土配合物的合成与表征

刘国发;赵永年;刘晓勋   

  1. 吉林大学材料科学研究所;吉林大学原子分子物理研究所;吉林大学分析测试中心
  • 发布日期:1992-05-15

Preparation and characterization of coordination compounds on rare earth nitrate with Schiff base derived from o-vanillin and 1-naphthylamine

LIU GUOFA;ZHAO YONGNIAN;LIU XIAOXUN   

  • Published:1992-05-15

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564

被引次数

16 | 3

合成邻香兰素(2-羟基-3-甲氧基苯甲醛)与α-萘胺Schiff碱硝酸稀土配合物[LnL~2(NO~3)~2]NO~3(Ln: 镧系元素, L: Schiff碱配体)。配合物由一个中心稀土离子, 两个Schiff碱和三个硝酸根组成, 两个Schiff碱都是氮、氧双配位, 两个硝酸根是双齿配位, 另一硝酸根在配合物外界。中心稀土离子是八配位的, 满足稀土八配位的稳定结构。

关键词: 苯甲醛 P, 分子结构, 硝酸盐, 钬络合物, 镱络合物, 萘胺 P, 镨络合物, 铕络合物, 镧络合物, 钕络合物

Coordination compounds of rare earth nitrates with the Schiff base derived from o-vanillin and 1-naphthylamine were prepared and characterized. On the basis of elemental anal., IR spectra, Raman spectra, UV-visible spectra, molar conductance and thermal anal., it is concluded that two Schiff bases (L) and two nitrate groups are bound to the rare earth ion. One nitrate group is in the outer coordination sphere; i.e. [LnL2(NO3)2]NO3 (Ln = La, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Tm, Yb). The lanthanide ions in the coordination compounds exhibit coordination no. eight.

Key words: BENZALDEHYDE P, MOLECULAR STRUCTURE, NITRATE, HOLMIUM COMPLEX, YTTERBIUM COMPLEX, NAPHTHALENEAMINE P, PRASEODYMIUM COMPLEX, EUROPIUM COMPLEX, LANTHANUM COMPLEX, NEODYMIUM COMPLEX

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