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化学学报
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化学学报 ›› 2009, Vol. 67 ›› Issue (6): 471-476. 上一篇    下一篇

研究论文

全钒氧化还原液流电池用Nafion/有机硅复合膜

滕祥国a 赵永涛a,b 席靖宇a 武增华a 邱新平*,a,b 陈立泉a,c

  

  1. (a清华大学深圳研究生院 绿色化学电源实验室 深圳 518055)
    (b清华大学化学系 有机光电子与分子工程重点实验室 北京 100084)
    (c中国科学院物理研究所 固体离子学实验室 北京 100080)

  • 投稿日期:2008-08-11 修回日期:2008-10-29 发布日期:2009-03-28
  • 通讯作者: 邱新平

Nafion/Organic Silica Hybrid Membrane for Vanadium Redox Flow Battery

Teng, Xiangguo a Zhao, Yongtao a,b Xi, Jingyu a Wu, Zenghua a
Qiu, Xinping *,a,b Chen, Liquan a,c
  

  1. (a Laboratory of Advanced Power Sources, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055)
    (b Key Laboratory of Organic Optoelectronics and Molecules, Tsinghua University, Beijing 100084)
    (c Laboratory for Solid State Ionics, Institute of Physics, Chinese Academy of Sciences, Beijing 100080)
  • Received:2008-08-11 Revised:2008-10-29 Published:2009-03-28
  • Contact: Qiu, Xinping

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被引次数

52 | 7

采用原位化学反应的方法制备了Nafion/有机硅复合膜, 并对所制备复合膜的离子交换容量(IEC)、电导率和水渗透率等进行了测试. 结果表明, 所制备复合膜具有优异的阻水性能. 以Nafion/有机硅复合膜作为离子交换膜的钒电池的库仑效率(CE)和能量效率(EE)都得到了大幅度提高. 此外, 以所制备复合膜为离子交换膜的VRB单电池充放电80次后性能几乎无衰减, 说明所制备Nafion/有机硅复合膜即使在强酸和强氧化性的钒电池体系中也可以稳定使用, 表明Nafion/有机硅复合膜是一种性能优异的适用于全钒氧化还原液流电池的新型质子交换膜.

关键词: 钒电池, Nafion, 有机硅复合膜

Nafion/organic silica hybrid membrane was prepared via an in situ sol-gel reaction method and the ion exchange capacity (IEC), conductivity and water transport rate of the hybrid membrane were measured. Results indicate that compared with Nafion membrane, the hybrid membrane can efficiently block water transfer across the membrane. The average coulombic efficiency and energy efficiency of the VRB with the Nafion/organic silica membrane were all remarkably increased. Furthermore, the Nafion/organic silica hybrid membrane is very stable for more than 80 charge-discharge cycles at current density of 60 mA•cm−2. Results show that the Nafion/organic silica membrane is a novel hybrid membrane and applicable to VRB.

Key words: vanadium redox flow battery, Nafion, organic silica hybrid membrane